Ion association has been investigated by Raman scattering from triflate salts M(CF3SO3)x in PEO (400) for various cationic substitutions (M = Li+, Ca2+, Cu2+, and Nd3+) and for OH-capped, respectively CH3-capped, polymer chains. The ion-ion interaction shows different temperature behavior in different systems. The observations are discussed in terms of recent theories which consider volume changes (electrostriction) in the salt dissociation process.

Ionic interactions in MCF3SO3-polyether complexes containing mono-, di- and trivalent cations / G., Petersen; L. M., Torell; Panero, Stefania; Scrosati, Bruno; C. J., da Silva; M., Smith. - In: SOLID STATE IONICS. - ISSN 0167-2738. - STAMPA. - 60:1-3(1993), pp. 55-60. [10.1016/0167-2738(93)90274-7]

Ionic interactions in MCF3SO3-polyether complexes containing mono-, di- and trivalent cations

PANERO, Stefania;SCROSATI, Bruno;
1993

Abstract

Ion association has been investigated by Raman scattering from triflate salts M(CF3SO3)x in PEO (400) for various cationic substitutions (M = Li+, Ca2+, Cu2+, and Nd3+) and for OH-capped, respectively CH3-capped, polymer chains. The ion-ion interaction shows different temperature behavior in different systems. The observations are discussed in terms of recent theories which consider volume changes (electrostriction) in the salt dissociation process.
1993
ion association; Raman spectroscopy; di and trivalent cations
01 Pubblicazione su rivista::01a Articolo in rivista
Ionic interactions in MCF3SO3-polyether complexes containing mono-, di- and trivalent cations / G., Petersen; L. M., Torell; Panero, Stefania; Scrosati, Bruno; C. J., da Silva; M., Smith. - In: SOLID STATE IONICS. - ISSN 0167-2738. - STAMPA. - 60:1-3(1993), pp. 55-60. [10.1016/0167-2738(93)90274-7]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/461357
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