A nuclear technique based on the spontaneous decay of tritiated precursors has been used in a comparative study of arom. phenylation by free phenylium ions, both in the gas and liq. phase. Thus, tritiated phenylium cation (I) was used to phenylate RPh (R = Cl, F, OMe, Ph) both in the gas and liq. phases. The mechanism of the major competitive processes promoted by phenylium ion attack are discussed.
AROMATIC-HYDROCARBONS IN THE GASEOUS AND CONDENSED PHASE - A NUCLEAR DECAY STUDY / Angelini, Giancarlo; Y., Keheyan; Speranza, Maurizio. - In: BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE. - ISSN 0037-8968. - STAMPA. - (1988), pp. 367-370.
AROMATIC-HYDROCARBONS IN THE GASEOUS AND CONDENSED PHASE - A NUCLEAR DECAY STUDY
ANGELINI, Giancarlo;SPERANZA, Maurizio
1988
Abstract
A nuclear technique based on the spontaneous decay of tritiated precursors has been used in a comparative study of arom. phenylation by free phenylium ions, both in the gas and liq. phase. Thus, tritiated phenylium cation (I) was used to phenylate RPh (R = Cl, F, OMe, Ph) both in the gas and liq. phases. The mechanism of the major competitive processes promoted by phenylium ion attack are discussed.File allegati a questo prodotto
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