Electrophilic substitution of pyrrole with 3HeT+, Me2F+, and Me3C+ in the gas phase occurred predominantly at the β-C atom. E.g., gas-phase reaction of pyrrole with Me3C+, generated by radiolysis of CMe4, gave a 7:21:72 mixt. of N-, α-, and β-tert-butylpyrrole.
First example of predominant β-orientation in electrophilic substitution of pyrrole / Speranza, Maurizio. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - STAMPA. - 22(1981), pp. 1177-1178.
First example of predominant β-orientation in electrophilic substitution of pyrrole
SPERANZA, Maurizio
1981
Abstract
Electrophilic substitution of pyrrole with 3HeT+, Me2F+, and Me3C+ in the gas phase occurred predominantly at the β-C atom. E.g., gas-phase reaction of pyrrole with Me3C+, generated by radiolysis of CMe4, gave a 7:21:72 mixt. of N-, α-, and β-tert-butylpyrrole.File allegati a questo prodotto
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