Ion-assisted dehalogenation of halobenzenes provided a convenient source for Ph+ ions. Gas-phase reactions of Ph+ with H, alkanes, alkyl halides, alkenes and arenes were studied by ion cyclotron resonance spectroscopy. Ph+ is a strong electrophile, attacking σ as well as π and nonbonding electrons. The reactivity of Ph+ has carbenoid characteristics.
Phenylium (C6H5+) ion-molecule reactions studied by ion cyclotron resonance spectroscopy / Speranza, Maurizio; M. D., Sefcik; J. M. S., Henis; P. P., Gaspar. - In: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. - ISSN 0002-7863. - STAMPA. - 99:(1977), pp. 5583-5589.
Phenylium (C6H5+) ion-molecule reactions studied by ion cyclotron resonance spectroscopy
SPERANZA, Maurizio;
1977
Abstract
Ion-assisted dehalogenation of halobenzenes provided a convenient source for Ph+ ions. Gas-phase reactions of Ph+ with H, alkanes, alkyl halides, alkenes and arenes were studied by ion cyclotron resonance spectroscopy. Ph+ is a strong electrophile, attacking σ as well as π and nonbonding electrons. The reactivity of Ph+ has carbenoid characteristics.File allegati a questo prodotto
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