Biomimetic and enzymatic oxidations of benzyl sulfides and sulfoxides lead to products (sulfoxides or sulfones) different from those obtained with bona fide electron transfer oxidations (products of C-H and/or C-S bond cleavage), which suggests the operation of an oxygen transfer mechanism.
THE MECHANISM OF ENZYMATIC AND BIOMIMETIC OXIDATIONS OF AROMATIC SULFIDES AND SULFOXIDES / Enrico, Baciocchi; Lanzalunga, Osvaldo; Francesco, Marconi. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - STAMPA. - 35:52(1994), pp. 9771-9774. [10.1016/0040-4039(94)88382-3]
THE MECHANISM OF ENZYMATIC AND BIOMIMETIC OXIDATIONS OF AROMATIC SULFIDES AND SULFOXIDES
LANZALUNGA, Osvaldo;
1994
Abstract
Biomimetic and enzymatic oxidations of benzyl sulfides and sulfoxides lead to products (sulfoxides or sulfones) different from those obtained with bona fide electron transfer oxidations (products of C-H and/or C-S bond cleavage), which suggests the operation of an oxygen transfer mechanism.File allegati a questo prodotto
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