Complexes formed by the dianions LH2- and L'2- deriving from dihydrolipoic acid (LH3) and dihydrolipoamide (L'H2), respectively, by substitution of the hydrogen atoms of the thiol groups with Ni(II), Co(II), Hg(II) and Cu(I) ions were synthesized, isolated and characterized. In all these compounds the metal ions are coordinated to the thiolic sulfur atoms of the ligands. Potentiometric and spectroscopic data (IR, UV-Vis, EPR and XPS) obtained for these complexes or for their solutions are discussed.

SYNTHESIS AND CHARACTERIZATION OF METAL DERIVATIVES OF DIHYDROLIPOIC ACID AND DIHYDROLIPOAMIDE / F., Bonomi; S., Pagani; F., Cariati; A., Pozzi; G., Crisponi; F., Cristiani; A., Diaz; Zanoni, Robertino. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - STAMPA. - 192:2(1992), pp. 237-242. [10.1016/s0020-1693(00)80765-3]

SYNTHESIS AND CHARACTERIZATION OF METAL DERIVATIVES OF DIHYDROLIPOIC ACID AND DIHYDROLIPOAMIDE

ZANONI, Robertino
1992

Abstract

Complexes formed by the dianions LH2- and L'2- deriving from dihydrolipoic acid (LH3) and dihydrolipoamide (L'H2), respectively, by substitution of the hydrogen atoms of the thiol groups with Ni(II), Co(II), Hg(II) and Cu(I) ions were synthesized, isolated and characterized. In all these compounds the metal ions are coordinated to the thiolic sulfur atoms of the ligands. Potentiometric and spectroscopic data (IR, UV-Vis, EPR and XPS) obtained for these complexes or for their solutions are discussed.
1992
01 Pubblicazione su rivista::01a Articolo in rivista
SYNTHESIS AND CHARACTERIZATION OF METAL DERIVATIVES OF DIHYDROLIPOIC ACID AND DIHYDROLIPOAMIDE / F., Bonomi; S., Pagani; F., Cariati; A., Pozzi; G., Crisponi; F., Cristiani; A., Diaz; Zanoni, Robertino. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - STAMPA. - 192:2(1992), pp. 237-242. [10.1016/s0020-1693(00)80765-3]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/458587
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