The morphological evolution of as-grown poly(phenylacetylene) (PPA) free standing films has been studied. Investigations performed by scanning electron microscopy show that the freshly prepared PPA films exhibit a glass-like morphology which subsequently evolves into a microsphere structure. After ageing for 3 months at room temperature, PPA films reach a stable enamel-like phase. The chemical structure of the Rh(I) catalysts does not appear to influence the morphology of PPA. However, different catalysts yield different rates of morphological evolution.

Morphological-study of Poly(phenylacetylene) Films, Prepared With Rh(i) Catalysts, From Scanning Microscopy Investigations / Russo, Maria Vittoria; G., Iucci; D., Ferro. - In: POLYMER. - ISSN 0032-3861. - 34:(1993), pp. 257-261. [10.1016/0032-3861(93)90075-L]

Morphological-study of Poly(phenylacetylene) Films, Prepared With Rh(i) Catalysts, From Scanning Microscopy Investigations

RUSSO, Maria Vittoria;
1993

Abstract

The morphological evolution of as-grown poly(phenylacetylene) (PPA) free standing films has been studied. Investigations performed by scanning electron microscopy show that the freshly prepared PPA films exhibit a glass-like morphology which subsequently evolves into a microsphere structure. After ageing for 3 months at room temperature, PPA films reach a stable enamel-like phase. The chemical structure of the Rh(I) catalysts does not appear to influence the morphology of PPA. However, different catalysts yield different rates of morphological evolution.
1993
PHYSICAL-PROPERTIES; POLYACETYLENE; CONDUCTIVITY
01 Pubblicazione su rivista::01a Articolo in rivista
Morphological-study of Poly(phenylacetylene) Films, Prepared With Rh(i) Catalysts, From Scanning Microscopy Investigations / Russo, Maria Vittoria; G., Iucci; D., Ferro. - In: POLYMER. - ISSN 0032-3861. - 34:(1993), pp. 257-261. [10.1016/0032-3861(93)90075-L]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/458486
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