Replacing triethylamine by heterogeneous inorganic bases makes it possible to aminate benzene or other nitrene accepters, using the title reagent, previously reported to be scarcely reactive. Products of C-H insertion and/or those coming from intermediate aziridines are also obtained.
CS2CO3 OR CAO AS PROMOTERS OF ETHYL N-([(4-METHYLPHENYL)SULPHONYL]OXY)CARBAMATE IN AMINATION REACTIONS / Marco, Barani; Fioravanti, Stefania; Pellacani, Lucio; Tardella, Paolo Antonio. - In: TETRAHEDRON. - ISSN 0040-4020. - STAMPA. - 50:38(1994), pp. 11235-11238. [10.1016/s0040-4020(01)89425-4]
CS2CO3 OR CAO AS PROMOTERS OF ETHYL N-([(4-METHYLPHENYL)SULPHONYL]OXY)CARBAMATE IN AMINATION REACTIONS
FIORAVANTI, Stefania;PELLACANI, Lucio;TARDELLA, Paolo Antonio
1994
Abstract
Replacing triethylamine by heterogeneous inorganic bases makes it possible to aminate benzene or other nitrene accepters, using the title reagent, previously reported to be scarcely reactive. Products of C-H insertion and/or those coming from intermediate aziridines are also obtained.File allegati a questo prodotto
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