The synthesis of N-ethoxycarbonyl-7-azabicyclo[4.2.1]nonane and iV-ethoxycarbonyl-9-azabicyclo[4.2.1]nonane, starting from bicyclo[5.1.0]octan- 2-one, is described. The key step is the cyclopropyl ring fission by pyridinium chloride. © HeteroCorporation.
Synthesis of N-ethoxycarbonyl-7-azabicyclo[4.2.1]nonane and N-ethoxycarbonyl-9-azabicyclo[4.2.1]nonane (1) / Loreto, Maria Antonietta; Pellacani, Lucio; Tardella, Paolo Antonio. - In: JOURNAL OF HETEROCYCLIC CHEMISTRY. - ISSN 0022-152X. - 16:(1979), pp. 1233-1234. [10.1002/jhet.5570160628]
Synthesis of N-ethoxycarbonyl-7-azabicyclo[4.2.1]nonane and N-ethoxycarbonyl-9-azabicyclo[4.2.1]nonane (1)
LORETO, Maria Antonietta;PELLACANI, Lucio;TARDELLA, Paolo Antonio
1979
Abstract
The synthesis of N-ethoxycarbonyl-7-azabicyclo[4.2.1]nonane and iV-ethoxycarbonyl-9-azabicyclo[4.2.1]nonane, starting from bicyclo[5.1.0]octan- 2-one, is described. The key step is the cyclopropyl ring fission by pyridinium chloride. © HeteroCorporation.File allegati a questo prodotto
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