The thin-layer chromatog. plates, precoated with silica gel, were derivatized by soaking in a soln. of glycidoxypropyltrimethoxy silane in toluene at 110°. After 45 min reaction, the plates were washed with benzene, then with MeOH, and dried. The plates were used to sep. a series of strictly related trans-[PdCl2L2] complexes, where L = hydrazone. The plates were also used to study the reaction of ligand exchange in soln. between Pd complexes with different ligands [trans-(PdCl2L2) and trans-(PdCl2L'2)] and the formation of the mixed complex trans-(PdCl2LL'). [on SciFinder(R)]
Thin-layer chromatography of metal complexes on glycidoxypropyl functionalized silica plates / Galli, Beatrice; Gasparrini, Francesco; Misiti, Domenico; G., Natile; G., Palmieri. - In: JOURNAL OF CHROMATOGRAPHY. - ISSN 0021-9673. - STAMPA. - 409:(1987), pp. 377-382. [10.1016/S0021-9673(01)86816-3]
Thin-layer chromatography of metal complexes on glycidoxypropyl functionalized silica plates
GALLI, Beatrice;GASPARRINI, Francesco;MISITI, Domenico;
1987
Abstract
The thin-layer chromatog. plates, precoated with silica gel, were derivatized by soaking in a soln. of glycidoxypropyltrimethoxy silane in toluene at 110°. After 45 min reaction, the plates were washed with benzene, then with MeOH, and dried. The plates were used to sep. a series of strictly related trans-[PdCl2L2] complexes, where L = hydrazone. The plates were also used to study the reaction of ligand exchange in soln. between Pd complexes with different ligands [trans-(PdCl2L2) and trans-(PdCl2L'2)] and the formation of the mixed complex trans-(PdCl2LL'). [on SciFinder(R)]I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
