N-Alky-N'-tosylhydrazines upon treatment with H2O2 and Na2O2 give with high yields the corresponding aliphatic hydroperoxides. A discussion on the possible reaction mechanism which involves the formation of an "ion pair" intermediate, is reported. The reaction of tosylhydrazones carried out under simular conditions to give dihydroperoxides and other compounds is also described.
Oxidation of-N-alkyl-N'-tosylhydrazines to hydroperoxides / Caglioti, Luciano; Gasparrini, Francesco; Misiti, Domenico; G., Palmieri. - In: TETRAHEDRON. - ISSN 0040-4020. - STAMPA. - 34:(1978), pp. 135-139. [10.1016/0040-4020(78)88048-X]
Oxidation of-N-alkyl-N'-tosylhydrazines to hydroperoxides
CAGLIOTI, Luciano;GASPARRINI, Francesco;MISITI, Domenico;
1978
Abstract
N-Alky-N'-tosylhydrazines upon treatment with H2O2 and Na2O2 give with high yields the corresponding aliphatic hydroperoxides. A discussion on the possible reaction mechanism which involves the formation of an "ion pair" intermediate, is reported. The reaction of tosylhydrazones carried out under simular conditions to give dihydroperoxides and other compounds is also described.File allegati a questo prodotto
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