Newly synthesized trans-[PdCl2(R1R2C[double bond, length half m-dash]N1–N2R3R4)2] complexes have a high Pd–N1 rotational barrier which, in solution, gives rise to two isomers depending on the relative orientations of the hydrazone molecules with respect to each other (symmetrical in one isomer and asymmetrical in the other).
High barrier to rotation about the Pd-N bond in trans-dichloro-dihydrazone-palladium(II) complexes / G., Natile; L., Cattalini; Gasparrini, Francesco. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - STAMPA. - (1977), pp. 89-90. [10.1039/C39770000089]
High barrier to rotation about the Pd-N bond in trans-dichloro-dihydrazone-palladium(II) complexes
GASPARRINI, Francesco
1977
Abstract
Newly synthesized trans-[PdCl2(R1R2C[double bond, length half m-dash]N1–N2R3R4)2] complexes have a high Pd–N1 rotational barrier which, in solution, gives rise to two isomers depending on the relative orientations of the hydrazone molecules with respect to each other (symmetrical in one isomer and asymmetrical in the other).File allegati a questo prodotto
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