R(NH)2O2SC6H4Me-4 [R = Me3CCH2, Me(CH2)15, cyclohexyl, 2-methylcyclohexyl, 5α-cholestan-3β-yl, 17β-hydroxyandrostan-3-yl, 17β-acetoxyandrostanyl] underwent H2O2/Na2O2 oxidn. in THF at room temp. to give 87-95% ROOH. A reaction mechanism is postulated involving formation of a p-tolylsulfonylazaalkane, present in the reaction medium in the form of an ion-pair [RN+≡N 4-MeC6H4SO2-].
Oxidation of-N-alkyl-N'-tosylhydrazines. A new, convenient synthesis of hydroperoxides / Caglioti, L., Gasparrini, F., Misiti, D., G., P.. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - STAMPA. - 17:(1976), pp. 3987-3988. [10.1016/S0040-4039(00)92555-3]
Oxidation of-N-alkyl-N'-tosylhydrazines. A new, convenient synthesis of hydroperoxides
CAGLIOTI, Luciano;GASPARRINI, Francesco;MISITI, Domenico;
1976
Abstract
R(NH)2O2SC6H4Me-4 [R = Me3CCH2, Me(CH2)15, cyclohexyl, 2-methylcyclohexyl, 5α-cholestan-3β-yl, 17β-hydroxyandrostan-3-yl, 17β-acetoxyandrostanyl] underwent H2O2/Na2O2 oxidn. in THF at room temp. to give 87-95% ROOH. A reaction mechanism is postulated involving formation of a p-tolylsulfonylazaalkane, present in the reaction medium in the form of an ion-pair [RN+≡N 4-MeC6H4SO2-].File allegati a questo prodotto
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