Aliphatic tosylhydrazides upon treatment with diborane followed by alkaline hydrolysis yield aliphatic hydrocarbons. Aromatic hydrocarbons are produced when aromatic tosylhydrazides undergo heating in presence of diborane and are subsequently oxidated by KIO4. A discussion on the structures of intermediate products is reported
Reduction of N-acyl, N'-tosylhydrazines with diborane. A simple, convenient procedure for the conversion of the carboxylic to the methyl group / O., Attanasi; Caglioti, Luciano; Gasparrini, Francesco; Misiti, Domenico. - In: TETRAHEDRON. - ISSN 0040-4020. - STAMPA. - 31:(1975), pp. 341-345. [10.1016/0040-4020(75)80043-3]
Reduction of N-acyl, N'-tosylhydrazines with diborane. A simple, convenient procedure for the conversion of the carboxylic to the methyl group
CAGLIOTI, Luciano;GASPARRINI, Francesco;MISITI, Domenico
1975
Abstract
Aliphatic tosylhydrazides upon treatment with diborane followed by alkaline hydrolysis yield aliphatic hydrocarbons. Aromatic hydrocarbons are produced when aromatic tosylhydrazides undergo heating in presence of diborane and are subsequently oxidated by KIO4. A discussion on the structures of intermediate products is reportedI documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
