The ligand biacetyl-bis(N-methyl, -N-phenyl)-osazone (L) coordinated to palladium(II) to form the complex [PdLCl2] undergoes hydrogen chloride elimination to give a monomer [Pd(L-H)Cl], containing a carbon-palladium covalent bond. The chemical properties of the two complexes are compared and discussed.
The chemical behaviour of biacetyl-bis-(N-methyl,N-phenyl)osazone coordinated to Pd(II) / Caglioti, Luciano; L., Cattalini; Gasparrini, Francesco; M., Ghedini; G., Paolucci; P. A., Vigato. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - STAMPA. - 7:(1973), pp. 538-540. [10.1016/S0020-1693(00)94879-5]
The chemical behaviour of biacetyl-bis-(N-methyl,N-phenyl)osazone coordinated to Pd(II)
CAGLIOTI, Luciano;GASPARRINI, Francesco;
1973
Abstract
The ligand biacetyl-bis(N-methyl, -N-phenyl)-osazone (L) coordinated to palladium(II) to form the complex [PdLCl2] undergoes hydrogen chloride elimination to give a monomer [Pd(L-H)Cl], containing a carbon-palladium covalent bond. The chemical properties of the two complexes are compared and discussed.File allegati a questo prodotto
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