New complexes of palladium(II) containing as ligands R-azo-cyclohexene derivatives have been prepared. Their characterisation by way of various physical-chemical techniques, including 1H n.m.r. and i.r. spectra, indicate that they are all neutral complexes of the type trans-PdL2Cl2 and that the co-ordination occurs through a nitrogen–palladium σ-bond. Some aspects of their chemical properties are also reported and discussed.
Palladium(II) complex of azocyclohexene derivatives / Caglioti, Luciano; L., Cattalini; Gasparrini, Francesco; G., Marangoni; A., Vigato. - In: JOURNAL OF THE CHEMICAL SOCIETY. A. INORGANIC, PHYSICAL, THEORETICAL. - ISSN 0022-4944. - STAMPA. - (1971), pp. 324-326. [10.1039/J19710000324]
Palladium(II) complex of azocyclohexene derivatives
CAGLIOTI, Luciano;GASPARRINI, Francesco;
1971
Abstract
New complexes of palladium(II) containing as ligands R-azo-cyclohexene derivatives have been prepared. Their characterisation by way of various physical-chemical techniques, including 1H n.m.r. and i.r. spectra, indicate that they are all neutral complexes of the type trans-PdL2Cl2 and that the co-ordination occurs through a nitrogen–palladium σ-bond. Some aspects of their chemical properties are also reported and discussed.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
