The efficiency of the gas phase hydride ion transfer from 2,2-dimethylbutane to tert-butyl cation displays a pronounced positive pressure dependence, which suggests significant anchimeric assistance of the methyl groups of 2,2-dimethylbutane adjacent to the departing CH2 hydride in the transition state
Hydride Ion Transfer Reaction in the Gas Phase. 1. Pressure Dependence of the Reaction Efficiency as a Criterion to Recognize Anchimeric Assistance / Crestoni, Maria Elisa; Fornarini, Simonetta; Massimo, Lentini; Speranza, Maurizio. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - (1995), pp. 121-122. [10.1039/c39950000121]
Hydride Ion Transfer Reaction in the Gas Phase. 1. Pressure Dependence of the Reaction Efficiency as a Criterion to Recognize Anchimeric Assistance
CRESTONI, Maria Elisa;FORNARINI, Simonetta;SPERANZA, Maurizio
1995
Abstract
The efficiency of the gas phase hydride ion transfer from 2,2-dimethylbutane to tert-butyl cation displays a pronounced positive pressure dependence, which suggests significant anchimeric assistance of the methyl groups of 2,2-dimethylbutane adjacent to the departing CH2 hydride in the transition stateI documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
