The efficiency of the gas phase hydride ion transfer from 2,2-dimethylbutane to tert-butyl cation displays a pronounced positive pressure dependence, which suggests significant anchimeric assistance of the methyl groups of 2,2-dimethylbutane adjacent to the departing CH2 hydride in the transition state

Hydride Ion Transfer Reaction in the Gas Phase. 1. Pressure Dependence of the Reaction Efficiency as a Criterion to Recognize Anchimeric Assistance / Crestoni, Maria Elisa; Fornarini, Simonetta; Massimo, Lentini; Speranza, Maurizio. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - (1995), pp. 121-122. [10.1039/c39950000121]

Hydride Ion Transfer Reaction in the Gas Phase. 1. Pressure Dependence of the Reaction Efficiency as a Criterion to Recognize Anchimeric Assistance

CRESTONI, Maria Elisa;FORNARINI, Simonetta;SPERANZA, Maurizio
1995

Abstract

The efficiency of the gas phase hydride ion transfer from 2,2-dimethylbutane to tert-butyl cation displays a pronounced positive pressure dependence, which suggests significant anchimeric assistance of the methyl groups of 2,2-dimethylbutane adjacent to the departing CH2 hydride in the transition state
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/452223
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