In both the pyrrole and benzene ring the methoxy denitration reaction is accelerated by a nitro or a cyano group flanking the reaction center. However, because of the different geometry of the rings, in the pyrrole ring a nitro group is more effective than a cyano group, at variance with what is observed in the benzene ring.
Cyano and Nitro Group Effect on the Rate of Methoxy Denitration Reaction in the Pyrrole and Benzene Ring / Bazzano, F.; Mencarelli, Paolo; Stegel, F.. - In: JOURNAL OF ORGANIC CHEMISTRY. - ISSN 0022-3263. - STAMPA. - 49:(1984), pp. 2375-2377. [10.1021/jo00187a014]
Cyano and Nitro Group Effect on the Rate of Methoxy Denitration Reaction in the Pyrrole and Benzene Ring
MENCARELLI, Paolo;
1984
Abstract
In both the pyrrole and benzene ring the methoxy denitration reaction is accelerated by a nitro or a cyano group flanking the reaction center. However, because of the different geometry of the rings, in the pyrrole ring a nitro group is more effective than a cyano group, at variance with what is observed in the benzene ring.File allegati a questo prodotto
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