6-Exo-dig and/or 7-endo-dig iodocyclization reactions of functionalized acetylenic derivatives with ICl are disfavored in comparison with the corresponding electrophilic addition reactions providing regioselectively (E)-1- chloro-2-iodoethene derivatives. On the contrary, 6-endo-dig and 5-exo-dig iodocyclizations of methyl ynoates with ICl seem to be favored in comparison with the corresponding electrophilic addition reactions.
Reaction of Alkynes with Iodine Monochloride Revisited / F., Bellina; F., Colzi; Mannina, Luisa; R. ROSSI S., Viel. - In: JOURNAL OF ORGANIC CHEMISTRY. - ISSN 0022-3263. - ELETTRONICO. - 68(2003), pp. 10175-10177. [10.1021/jo035372f]
Scheda prodotto non validato
Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo
Titolo: | Reaction of Alkynes with Iodine Monochloride Revisited | |
Autori: | ||
Data di pubblicazione: | 2003 | |
Rivista: | ||
Citazione: | Reaction of Alkynes with Iodine Monochloride Revisited / F., Bellina; F., Colzi; Mannina, Luisa; R. ROSSI S., Viel. - In: JOURNAL OF ORGANIC CHEMISTRY. - ISSN 0022-3263. - ELETTRONICO. - 68(2003), pp. 10175-10177. [10.1021/jo035372f] | |
Handle: | http://hdl.handle.net/11573/42876 | |
Appartiene alla tipologia: | 01a Articolo in rivista |