“STEREOCONTROLLED SYNTHESIS OF CARBON-CARBON DOUBLE BOND LOCKED ANALOGUES OF STROBILURINS WHICH ARE CHARACTERIZED BY A TRANS-1,2-DISUBSTITUTED CYCLOPROPANE RING”
 TETRAHEDRON

Rossi, R.; Carpita, A.; Ribecai, A.; Mannina, Luisa

doi:10.1016/S0040-4020(01)00136-3

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The of four new carbon-carbon double bond locked analogues of strobilurins, which are characterized by a trans-1,2-disubstituted cyclopropane ring, have been synthesized according to a strategy which involves palladium-catalyzed cross-coupling reactions between methyl (Z)-2-iodo-3-methoxypropenoate and organometallic derivatives such as (1Rp,2Rp)-2-phenylcyclopropylboronic acid and (1Rp,2R)-1-(2-bromozinciophenyl)-2-arylcyclopropanes. The boronic acid has been prepared via cyclopropanation of (E)-2-phenylethenyl- 1,3,2-dioxaborinane and the organozinc compounds have been synthesized from easily available (E)-2-bromostilbenes.

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Titolo:	“STEREOCONTROLLED SYNTHESIS OF CARBON-CARBON DOUBLE BOND LOCKED ANALOGUES OF STROBILURINS WHICH ARE CHARACTERIZED BY A TRANS-1,2-DISUBSTITUTED CYCLOPROPANE RING” TETRAHEDRON
Autori:	R. ROSSI A. CARPITA A. RIBECAI MANNINA, LUISA mostra contributor esterni nascondi contributor esterni
Data di pubblicazione:	2001
Rivista:	TETRAHEDRON
Abstract:	The of four new carbon-carbon double bond locked analogues of strobilurins, which are characterized by a trans-1,2-disubstituted cyclopropane ring, have been synthesized according to a strategy which involves palladium-catalyzed cross-coupling reactions between methyl (Z)-2-iodo-3-methoxypropenoate and organometallic derivatives such as (1Rp,2Rp)-2-phenylcyclopropylboronic acid and (1Rp,2R)-1-(2-bromozinciophenyl)-2-arylcyclopropanes. The boronic acid has been prepared via cyclopropanation of (E)-2-phenylethenyl- 1,3,2-dioxaborinane and the organozinc compounds have been synthesized from easily available (E)-2-bromostilbenes.
Handle:	http://hdl.handle.net/11573/42307
Appare nella tipologia:	01a Articolo in rivista

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