NaBH4 redn. of 1-methyl-4-cyanopyridinium iodide (I) in 1:1 H2O-MeOH gave 1-methyl-4-cyano-1,2,5,6-tetrahydropyridine, whereas similar redn. of I in a 0.8M NaOH-MeOH soln. gave a tricyclododecadiene (II).
Borohydride reduction of pyridinium salts. III.Formation of a Diels-Alder adduct in the reduction of 1-methyl-4-cyanopyridinium iodide / Liberatore, Felice; Casini, Antonio; Carelli, Vincenzo; Arnone, A.; Mondelli, R.. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - STAMPA. - 26:(1971), pp. 2381-2384.
Borohydride reduction of pyridinium salts. III.Formation of a Diels-Alder adduct in the reduction of 1-methyl-4-cyanopyridinium iodide.
LIBERATORE, Felice;CASINI, Antonio;CARELLI, Vincenzo;
1971
Abstract
NaBH4 redn. of 1-methyl-4-cyanopyridinium iodide (I) in 1:1 H2O-MeOH gave 1-methyl-4-cyano-1,2,5,6-tetrahydropyridine, whereas similar redn. of I in a 0.8M NaOH-MeOH soln. gave a tricyclododecadiene (II).File allegati a questo prodotto
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