The survey of gaseous ions by vibrational spectroscopy is a rapidly growing field, taking advantage from the development of widely tunable infrared laser sources. The so-obtained IR multiple photon dissociation (IRMPD) spectroscopy may now easily cover a wide portion of the vibrational spectrum ranging from the mid-IR (fingerprint region) to the X-H (X = C,N,O) stretching region. This methodology, combined with kinetic studies of ion molecule reactions, offers a powerful tool to obtain information about ion structure and dynamics. An overview is given of few systems studied recently.
Infrared spectroscopy and structure elucidation of mass selected ions / Chiavarino, Barbara; Crestoni, Maria Elisa; Fornarini, Simonetta. - ELETTRONICO. - (2011). (Intervento presentato al convegno XXIV Congresso Nazionale della Società Chimica Italiana tenutosi a Lecce nel 11-16 settembre 2011).
Infrared spectroscopy and structure elucidation of mass selected ions
CHIAVARINO, Barbara;CRESTONI, Maria Elisa;FORNARINI, Simonetta
2011
Abstract
The survey of gaseous ions by vibrational spectroscopy is a rapidly growing field, taking advantage from the development of widely tunable infrared laser sources. The so-obtained IR multiple photon dissociation (IRMPD) spectroscopy may now easily cover a wide portion of the vibrational spectrum ranging from the mid-IR (fingerprint region) to the X-H (X = C,N,O) stretching region. This methodology, combined with kinetic studies of ion molecule reactions, offers a powerful tool to obtain information about ion structure and dynamics. An overview is given of few systems studied recently.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
