The vapor phase in equilibrium with cuprous chloride has been studied using the Knudsen effusion‐mass spectrometric technique. The polymeric species Cu3Cl3, Cu4Cl4, and Cu5Cl5 were observed, the first two in comparable amounts. Partial pressures and heats of vaporization for each species were measured: The atomization energies for these molecules calculated on the basis of the Rittner ionic model are compared with the experimental values.
Mass spectrometric study of the vaporization of cuprous chloride and the dissociation energy of Cu3Cl3, Cu4Cl4 and Cu5Cl5 / M., Guido; Balducci, Giovanni; Gigli, Guido; Spoliti, Maurizio. - In: THE JOURNAL OF CHEMICAL PHYSICS. - ISSN 0021-9606. - 55:9(1971), pp. 4566-4572. [10.1063/1.1676790]
Mass spectrometric study of the vaporization of cuprous chloride and the dissociation energy of Cu3Cl3, Cu4Cl4 and Cu5Cl5
BALDUCCI, Giovanni;GIGLI, Guido;SPOLITI, Maurizio
1971
Abstract
The vapor phase in equilibrium with cuprous chloride has been studied using the Knudsen effusion‐mass spectrometric technique. The polymeric species Cu3Cl3, Cu4Cl4, and Cu5Cl5 were observed, the first two in comparable amounts. Partial pressures and heats of vaporization for each species were measured: The atomization energies for these molecules calculated on the basis of the Rittner ionic model are compared with the experimental values.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
