Cylindrical coordinates and symmetries of regular enantiomeric sequences were derived on the basis of eigenvalue-eigenvectors solns. to the Eyring-transformation matrix, and were used to show that the general structure of conformationally equiv. enantiomers was a ring. Helical structures could be formed in the case of quasi-conformational equivalence between the monomeric units. For regular L,D copolypeptides, these helical structures were stabilized by both van der Waals and H bond interactions, and were more stable than the α-helix in the absence of configurational disorder.

Conformational Analysis of Regular Enantiomeric Sequences / DE SANTIS, Pasquale; Morosetti, Stefano; R., Rizzo. - In: MACROMOLECULES. - ISSN 0024-9297. - STAMPA. - 7:1(1974), pp. 52-58. [10.1021/ma60037a011]

Conformational Analysis of Regular Enantiomeric Sequences

DE SANTIS, Pasquale;MOROSETTI, Stefano;
1974

Abstract

Cylindrical coordinates and symmetries of regular enantiomeric sequences were derived on the basis of eigenvalue-eigenvectors solns. to the Eyring-transformation matrix, and were used to show that the general structure of conformationally equiv. enantiomers was a ring. Helical structures could be formed in the case of quasi-conformational equivalence between the monomeric units. For regular L,D copolypeptides, these helical structures were stabilized by both van der Waals and H bond interactions, and were more stable than the α-helix in the absence of configurational disorder.
1974
conformational analysis; d copolypeptides; l; regular enantiomeric sequences
01 Pubblicazione su rivista::01a Articolo in rivista
Conformational Analysis of Regular Enantiomeric Sequences / DE SANTIS, Pasquale; Morosetti, Stefano; R., Rizzo. - In: MACROMOLECULES. - ISSN 0024-9297. - STAMPA. - 7:1(1974), pp. 52-58. [10.1021/ma60037a011]
File allegati a questo prodotto
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/382565
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 197
  • ???jsp.display-item.citation.isi??? ND
social impact