Formation, optical properties and structures of bis(o-hydroxybenzylideneamine)copper(II) chelates of poly(L-lysine), poly(L-ornithine), and poly(L-α,β-diaminobutyric acid) were investigated. Experimental evidence was obtained for a definite structure of these polycomplexes in alcoholic/aqueous solution. Structural features showed that asymmetric polypeptide matrices bind metal chelates stereospecifically. On the basis of these results stereoselective reactions on bis(o-hydroxybenzylideneamine)copper(II) polycomplexes are expected.
FORMATION, PROPERTIES AND STRUCTURES OF BIS (ORTHO HYDROXYBENZYLIDENEAMINE)COPPER(II) CHELATES OF POLYPEPTIDE LIGANDS / Dentini, Mariella; DE SANTIS, Pasquale; Savino, Maria; A. S., Verdini. - In: DIE MAKROMOLEKULARE CHEMIE. - ISSN 0025-116X. - 175:(1974), pp. 327-337. [10.1002/macp.1974.021750201]
FORMATION, PROPERTIES AND STRUCTURES OF BIS (ORTHO HYDROXYBENZYLIDENEAMINE)COPPER(II) CHELATES OF POLYPEPTIDE LIGANDS
DENTINI, Mariella;DE SANTIS, Pasquale;SAVINO, Maria;
1974
Abstract
Formation, optical properties and structures of bis(o-hydroxybenzylideneamine)copper(II) chelates of poly(L-lysine), poly(L-ornithine), and poly(L-α,β-diaminobutyric acid) were investigated. Experimental evidence was obtained for a definite structure of these polycomplexes in alcoholic/aqueous solution. Structural features showed that asymmetric polypeptide matrices bind metal chelates stereospecifically. On the basis of these results stereoselective reactions on bis(o-hydroxybenzylideneamine)copper(II) polycomplexes are expected.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.