Wavelength- and mass-selected resonant-enhanced two-photon ionization (R2PI) spectra of supersonically expanded (R)-1-phenyl-2,2,2-trifluoroethanol (FER) and its complexes with water, R- and S-2-aminobutane (AR/S) and R- and S-2-butanol (BR/S) are reported and discussed in the light of ab initio calcns. The effects of the fluorine atoms in these systems have been evaluated by comparing the results with the vibronic and mass spectra of their nonfluorinated analogs, i.e. adducts with (R)-phenyl-1-ethanol (ER).
Monosolvation effects in chiral fluoroorganic compounds: a R2PI study / Giardini, Anna; Rondino, Flaminia; Paladini, Alessandra; ANA R., Hortal; Satta, Mauro; Speranza, Maurizio; S., Piccirillo. - In: PHYSICA SCRIPTA. - ISSN 0031-8949. - STAMPA. - 78:(2008), pp. 058121-6 pp.. [10.1088/0031-8949/78/05/058121]
Monosolvation effects in chiral fluoroorganic compounds: a R2PI study
GIARDINI, Anna;RONDINO, Flaminia;PALADINI, Alessandra;SATTA, Mauro;SPERANZA, Maurizio;
2008
Abstract
Wavelength- and mass-selected resonant-enhanced two-photon ionization (R2PI) spectra of supersonically expanded (R)-1-phenyl-2,2,2-trifluoroethanol (FER) and its complexes with water, R- and S-2-aminobutane (AR/S) and R- and S-2-butanol (BR/S) are reported and discussed in the light of ab initio calcns. The effects of the fluorine atoms in these systems have been evaluated by comparing the results with the vibronic and mass spectra of their nonfluorinated analogs, i.e. adducts with (R)-phenyl-1-ethanol (ER).I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
