Whereas the parent uranyl salophen is catalytically inactive, its phenyl derivative effectively catalyses with turnover the reaction of benzoquinone with 1,3-cyclohexadiene, while showing no appreciable affinity towards reactants and product.
Exclusive transition state stabilization in the supramolecular catalysis of Diels-Alder reaction by a uranyl salophen complex / DALLA CORT, Antonella; Mandolini, Luigi; L., Schiaffino. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - STAMPA. - (2005), pp. 3867-3869. [10.1039/b504713g]
Exclusive transition state stabilization in the supramolecular catalysis of Diels-Alder reaction by a uranyl salophen complex
DALLA CORT, Antonella;MANDOLINI, Luigi;
2005
Abstract
Whereas the parent uranyl salophen is catalytically inactive, its phenyl derivative effectively catalyses with turnover the reaction of benzoquinone with 1,3-cyclohexadiene, while showing no appreciable affinity towards reactants and product.File allegati a questo prodotto
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