The R2PI-TOF spectra of supersonically expanded rare gas/chiral arene heteroclusters have been rationalized in terms of the distortion of the pi-electron density reflecting the different dipole and quadrupole momenta induced in the rare gas atoms by interaction with the opposite pi-faces of the chiral arene itself.
Dissymmetry effects on the laser spectroscopy of supersonically expanded rare gas/chiral arene heteroclusters / Filippi, Antonello; Giardini, Anna; Enrico, Marcantoni; Paladini, Alessandra; Susanna, Piccirillo; Gabriele, Renzi; Rondino, Flaminia; Graziella, Roselli; Satta, Mauro; Speranza, Maurizio. - In: PHYSICAL CHEMISTRY CHEMICAL PHYSICS. - ISSN 1463-9076. - STAMPA. - 9:14(2007), pp. 1676-1679. [10.1039/b702257n]
Dissymmetry effects on the laser spectroscopy of supersonically expanded rare gas/chiral arene heteroclusters
FILIPPI, Antonello;GIARDINI, Anna;PALADINI, Alessandra;RONDINO, Flaminia;SATTA, Mauro;SPERANZA, Maurizio
2007
Abstract
The R2PI-TOF spectra of supersonically expanded rare gas/chiral arene heteroclusters have been rationalized in terms of the distortion of the pi-electron density reflecting the different dipole and quadrupole momenta induced in the rare gas atoms by interaction with the opposite pi-faces of the chiral arene itself.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
