By combining experimental and theoretical approaches, we study the adsorption of pentacene on copper as a model for the coupling between aromatic molecules and metal surfaces. Our results for the interface electronic structure are not compatible with a purely physisorption picture, which is conventionally employed for such systems. Nay, we demonstrate electronic mixing between molecular orbitals and metal electronic states.

Mixing of electronic states in pentacene adsorption on copper / Andrea, Ferretti; Chiara, Baldacchini; Arrigo, Calzolari; Rosa Di, Felice; Alice, Ruini; Elisa, Molinari; Betti, Maria Grazia. - In: PHYSICAL REVIEW LETTERS. - ISSN 0031-9007. - 99:4(2007), p. 046802. [10.1103/physrevlett.99.046802]

Mixing of electronic states in pentacene adsorption on copper

BETTI, Maria Grazia
2007

Abstract

By combining experimental and theoretical approaches, we study the adsorption of pentacene on copper as a model for the coupling between aromatic molecules and metal surfaces. Our results for the interface electronic structure are not compatible with a purely physisorption picture, which is conventionally employed for such systems. Nay, we demonstrate electronic mixing between molecular orbitals and metal electronic states.
2007
01 Pubblicazione su rivista::01a Articolo in rivista
Mixing of electronic states in pentacene adsorption on copper / Andrea, Ferretti; Chiara, Baldacchini; Arrigo, Calzolari; Rosa Di, Felice; Alice, Ruini; Elisa, Molinari; Betti, Maria Grazia. - In: PHYSICAL REVIEW LETTERS. - ISSN 0031-9007. - 99:4(2007), p. 046802. [10.1103/physrevlett.99.046802]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/361971
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