Here we report on the complex nature of the phase diagram of N-alkyl-N-methylpiperidinium bis(trifluoromethanesulfonyl)imide ionic liquids using several complementary techniques and on their structural order in the molten state using small-wide angle x-ray scattering. The latter study indicates that the piperidinium aliphatic alkyl chains tend to aggregate, forming alkyl domains embedded into polar regions, similar to what we recently highlighted in the case of other ionic liquids. (C) 2009 American Institute of Physics. [DOI: 10.1063/1.3119977]
Nanoscale organization in piperidinium-based room temperature ionic liquids / Alessandro, Triolo; Russina, Olga; Barbara, Fazio; Giovanni Battista, Appetecchi; Maria, Carewska; Stefano, Passerini. - In: THE JOURNAL OF CHEMICAL PHYSICS. - ISSN 0021-9606. - STAMPA. - 130:16(2009), pp. 164521-164521. [10.1063/1.3119977]
Nanoscale organization in piperidinium-based room temperature ionic liquids
RUSSINA, OLGA;Stefano Passerini
2009
Abstract
Here we report on the complex nature of the phase diagram of N-alkyl-N-methylpiperidinium bis(trifluoromethanesulfonyl)imide ionic liquids using several complementary techniques and on their structural order in the molten state using small-wide angle x-ray scattering. The latter study indicates that the piperidinium aliphatic alkyl chains tend to aggregate, forming alkyl domains embedded into polar regions, similar to what we recently highlighted in the case of other ionic liquids. (C) 2009 American Institute of Physics. [DOI: 10.1063/1.3119977]I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.