We describe herein the synthesis and the electrochemical behaviour of a series of bis( ferrocenylethynyl) complexes of platinum( II). In all complexes, the electronic interaction between the redox-active iron cores of the ferrocenyl termini is small, indicating a moderate electronic delocalisation over the bis( cyclopentadienyl-acetylide) Pt chain.
Synthesis and characterisation of bis(ferrocenylethynyl) complexes of platinum(II) - A re-investigation of their electrochemical behaviour / Osella, D; Gobetto, R; Nervi, C; Ravera, M; D'Amato, R; Russo, Maria Vittoria. - In: INORGANIC CHEMISTRY COMMUNICATIONS. - ISSN 1387-7003. - 1:(1998), pp. 239-245. [10.1016/S1387-7003(98)00064-1]
Synthesis and characterisation of bis(ferrocenylethynyl) complexes of platinum(II) - A re-investigation of their electrochemical behaviour
RUSSO, Maria Vittoria
1998
Abstract
We describe herein the synthesis and the electrochemical behaviour of a series of bis( ferrocenylethynyl) complexes of platinum( II). In all complexes, the electronic interaction between the redox-active iron cores of the ferrocenyl termini is small, indicating a moderate electronic delocalisation over the bis( cyclopentadienyl-acetylide) Pt chain.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
