Amino acid enantiomers are separated by reverse-phase chromatography with an optically active polyamine/Cu(II) complex in the mobile phase. The polyamine was obtained by reaction of ( — )-trans-1,2-diaminocyclohexane with ethylene glycol diglycidyl ether; the complex with copper(II) ions was used in the eluent. Separation factors are reported for ten amino acids and four barbiturates.
"Separation of amino acid enantiomers by adding a chiral complex to the eluent" / Masia, P.; Nicoletti, I.; Sinibaldi, M.; Attanasio, D.; Messina, Antonella. - In: ANALYTICA CHIMICA ACTA. - ISSN 0003-2670. - STAMPA. - 204:(1988), pp. 145-150.
"Separation of amino acid enantiomers by adding a chiral complex to the eluent"
MESSINA, Antonella
1988
Abstract
Amino acid enantiomers are separated by reverse-phase chromatography with an optically active polyamine/Cu(II) complex in the mobile phase. The polyamine was obtained by reaction of ( — )-trans-1,2-diaminocyclohexane with ethylene glycol diglycidyl ether; the complex with copper(II) ions was used in the eluent. Separation factors are reported for ten amino acids and four barbiturates.File allegati a questo prodotto
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