A stereoselective/stereospecific synthesis of polysubstituted tetrahydronaphthols based on the Michael addition of ortho-lithiated stilbene oxides to α,β-unsaturated Fischer carbene complexes followed by an unusual cyclization of the corresponding intermediate in a 6-endo-tet mode is described.
An efficient route to tetrahydronaphthols via addition of ortho-lithiated stilbene oxides to alfa,beta-unsaturated Fischer carbene complexes / V., Capriati; S., Florio; R., Luisi; F. M., Perna; A., Salomone; Gasparrini, Francesco. - In: ORGANIC LETTERS. - ISSN 1523-7060. - STAMPA. - 7:(2005), pp. 4895-4898. [10.1021/ol0518176]
An efficient route to tetrahydronaphthols via addition of ortho-lithiated stilbene oxides to alfa,beta-unsaturated Fischer carbene complexes
GASPARRINI, Francesco
2005
Abstract
A stereoselective/stereospecific synthesis of polysubstituted tetrahydronaphthols based on the Michael addition of ortho-lithiated stilbene oxides to α,β-unsaturated Fischer carbene complexes followed by an unusual cyclization of the corresponding intermediate in a 6-endo-tet mode is described.File allegati a questo prodotto
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