The structures of cetylpyridiniumammonium bromide (CPyB) and cetylquinuclidinium bromide (CQB), two tetraalkylammonium bromide surfactants, are reported. In particular, whereas the structure solution of CPyB was carried out through conventional single-crystal diffractometry, the structure of CQB has been determined by means of powder diffractometry. CPyB crystallizes in P (1) over bar space group with cell parameters a = 7.618(2) Angstrom, b = 5.554(1) Angstrom, c = 27.474(7) Angstrom, alpha = 95.03(2)degrees, beta = 95.65(2)degrees, gamma = 100.89(2)degrees, V = 1129.2(5) Angstrom(3) (R = 0.066, wR = 0.054): CQB also in P (1) over bar with cell parameters a = 8.1395(8) Angstrom, b = 6.4475(7) Angstrom, c = 25.237(2) Angstrom, alpha = 99.921(6)degrees, beta = 93.123(9)degrees, gamma = 111.956(9)degrees, V = 1222.9(2) Angstrom(3) (R-p = 0.097, wR(p) = 0.128, R-exp = 0.078, and R(F-2) = 0.127).
Single crystal structure determination of cetylpyridiniumammonium bromide and Rietveld structure determination of cetylquinuclidinium bromide / Ballirano, Paolo; Caminiti, Ruggero; V. M., Coiro; G., Mancini; Maras, Adriana; Sadun, Claudia. - In: ZEITSCHRIFT FUR KRISTALLOGRAPHIE. - ISSN 0044-2968. - STAMPA. - 213:2(1998), pp. 123-129. [10.1524/zkri.1998.213.2.123]
Single crystal structure determination of cetylpyridiniumammonium bromide and Rietveld structure determination of cetylquinuclidinium bromide
BALLIRANO, Paolo;CAMINITI, Ruggero;MARAS, Adriana;SADUN, Claudia
1998
Abstract
The structures of cetylpyridiniumammonium bromide (CPyB) and cetylquinuclidinium bromide (CQB), two tetraalkylammonium bromide surfactants, are reported. In particular, whereas the structure solution of CPyB was carried out through conventional single-crystal diffractometry, the structure of CQB has been determined by means of powder diffractometry. CPyB crystallizes in P (1) over bar space group with cell parameters a = 7.618(2) Angstrom, b = 5.554(1) Angstrom, c = 27.474(7) Angstrom, alpha = 95.03(2)degrees, beta = 95.65(2)degrees, gamma = 100.89(2)degrees, V = 1129.2(5) Angstrom(3) (R = 0.066, wR = 0.054): CQB also in P (1) over bar with cell parameters a = 8.1395(8) Angstrom, b = 6.4475(7) Angstrom, c = 25.237(2) Angstrom, alpha = 99.921(6)degrees, beta = 93.123(9)degrees, gamma = 111.956(9)degrees, V = 1222.9(2) Angstrom(3) (R-p = 0.097, wR(p) = 0.128, R-exp = 0.078, and R(F-2) = 0.127).I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.