The energy dispersive (ED) variant of the conventional x-ray reflectivity (XR) provides an atomic scale determination of the morphological characteristics of thin films, such as their thickness and surface roughness. We report on the in situ EDXR measurements of the (minimal) morphological changes of ruthenium phthalocyanine gas sensing thin films. A series of reflectivity spectra have been collected, during the exposure of the films to a gas flux of nitrogen oxides (NOx) molecules. The measurements allowed a very high density time sampling of the evolution of the two morphological parameters, providing important information on the gas-film interaction. (C) 2003 American Institute of Physics.
Time-resolved energy dispersive x-ray reflectometry measurements on ruthenium phthalocyanine gas sensing films / V., Rossi Albertini; Amanda, Generosi; B., Paci; P., Perfetti; G., Rossi; A., Capobianchi; A. M., Paoletti; Caminiti, Ruggero. - In: APPLIED PHYSICS LETTERS. - ISSN 0003-6951. - STAMPA. - 82:22(2003), pp. 3868-3870. [10.1063/1.1579868]
Time-resolved energy dispersive x-ray reflectometry measurements on ruthenium phthalocyanine gas sensing films
CAMINITI, Ruggero
2003
Abstract
The energy dispersive (ED) variant of the conventional x-ray reflectivity (XR) provides an atomic scale determination of the morphological characteristics of thin films, such as their thickness and surface roughness. We report on the in situ EDXR measurements of the (minimal) morphological changes of ruthenium phthalocyanine gas sensing thin films. A series of reflectivity spectra have been collected, during the exposure of the films to a gas flux of nitrogen oxides (NOx) molecules. The measurements allowed a very high density time sampling of the evolution of the two morphological parameters, providing important information on the gas-film interaction. (C) 2003 American Institute of Physics.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.