The synthesis of a chiral carbamoyl azide derived from Oppolzer's sultam is described. The thermal and photochemical behaviour in the presence of simple alkenes as well as of masked ketones is also reported. Diastereoselective amination reactions have been observed giving different products. © 2001 Elsevier Science Ltd.
Synthesis of a new optically active carbamoyl azide and its use as an aminating agent / DEL SIGNORE, Giuseppe; Fioravanti, Stefania; Pellacani, Lucio; Tardella, Paolo Antonio. - In: TETRAHEDRON. - ISSN 0040-4020. - STAMPA. - 57:21(2001), pp. 4623-4627. [10.1016/s0040-4020(01)00383-0]
Synthesis of a new optically active carbamoyl azide and its use as an aminating agent
DEL SIGNORE, GIUSEPPE;FIORAVANTI, Stefania;PELLACANI, Lucio;TARDELLA, Paolo Antonio
2001
Abstract
The synthesis of a chiral carbamoyl azide derived from Oppolzer's sultam is described. The thermal and photochemical behaviour in the presence of simple alkenes as well as of masked ketones is also reported. Diastereoselective amination reactions have been observed giving different products. © 2001 Elsevier Science Ltd.File allegati a questo prodotto
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