Lignin peroxidase can catalyse the N-demethylation of N,N-dimethylanilines by an electron transfer mechanism, where the deprotonation of the intermediate radical cation is also an enzymatic process.
Oxidative N-demethylation of N,N-dimethylanilines catalysed by lignin peroxidase: a mechanistic insight by a kinetic deuterium isotope effect study / Baciocchi, Enrico; Gerini, Maria Francesca; Lanzalunga, Osvaldo; Lapi, Andrea; Simona, Mancinelli; Mencarelli, Paolo. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 5(2000), pp. 393-394. [10.1039/a908394d]
Oxidative N-demethylation of N,N-dimethylanilines catalysed by lignin peroxidase: a mechanistic insight by a kinetic deuterium isotope effect study
BACIOCCHI, Enrico;GERINI, Maria Francesca;LANZALUNGA, Osvaldo;LAPI, Andrea;MENCARELLI, Paolo
2000
Abstract
Lignin peroxidase can catalyse the N-demethylation of N,N-dimethylanilines by an electron transfer mechanism, where the deprotonation of the intermediate radical cation is also an enzymatic process.File allegati a questo prodotto
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