Using O-18 labelled reactants and/or solvent, the origin of the oxygen in the products of the oxidation of N-methylcarbazole by H2O2 catalysed by lignin peroxidase and a model compound has been determined, so getting important information about the mechanism of the oxidative N-demethylation of aromatic tertiary amines.

18(O) Incorporation in the Oxidation of N-methylcarbazole by Lignin Peroxidase and a Model Compound: a Mechanistic Insight into the Oxdiative N-demethylation of Aromatic Tertiary Amines / Baciocchi, Enrico; Gerini, Maria Francesca; Lapi, Andrea. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - STAMPA. - 2002:(2002), pp. 946-947. [10.1039/b201492k]

18(O) Incorporation in the Oxidation of N-methylcarbazole by Lignin Peroxidase and a Model Compound: a Mechanistic Insight into the Oxdiative N-demethylation of Aromatic Tertiary Amines

BACIOCCHI, Enrico;GERINI, Maria Francesca;LAPI, Andrea
2002

Abstract

Using O-18 labelled reactants and/or solvent, the origin of the oxygen in the products of the oxidation of N-methylcarbazole by H2O2 catalysed by lignin peroxidase and a model compound has been determined, so getting important information about the mechanism of the oxidative N-demethylation of aromatic tertiary amines.
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18(O) Incorporation in the Oxidation of N-methylcarbazole by Lignin Peroxidase and a Model Compound: a Mechanistic Insight into the Oxdiative N-demethylation of Aromatic Tertiary Amines / Baciocchi, Enrico; Gerini, Maria Francesca; Lapi, Andrea. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - STAMPA. - 2002:(2002), pp. 946-947. [10.1039/b201492k]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/255386
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