Eliminative ring opening of oxiranium ions is a relatively facile process in the gas phase. The reaction involves preliminary ring opening of the charged moiety favored by interaction of its acidic protons with the base. A combination of stereoelectronic and conformational factors accounts for the high stereoselectivity of the reaction.
Eliminative ring opening of oxiranium ions in the gas phase / Renzi, G; Roselli, G; Grandinetti, F; Filippi, Antonello; Speranza, Maurizio. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - STAMPA. - 39:(2000), pp. 1673-1676.
Eliminative ring opening of oxiranium ions in the gas phase
FILIPPI, Antonello;SPERANZA, Maurizio
2000
Abstract
Eliminative ring opening of oxiranium ions is a relatively facile process in the gas phase. The reaction involves preliminary ring opening of the charged moiety favored by interaction of its acidic protons with the base. A combination of stereoelectronic and conformational factors accounts for the high stereoselectivity of the reaction.File allegati a questo prodotto
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