The electrogenerated base of 2-pyrrolidone reacts with amines and anilines yielding the corresponding alkyl and aryl carbamates, after addition of carbon dioxide and ethyl iodide. Arylcarbamic esters are obtained in very good yields under mild reaction conditions with respect to the methods so far reported. (C) 2000 Elsevier Science Ltd. All rights reserved.
The reaction of amines with an electrogenerated base. Improved synthesis of arylcarbamic esters / Feroci, Marta; Inesi, Achille; Leucio, Rossi. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - STAMPA. - 41:6(2000), pp. 963-966. [10.1016/s0040-4039(99)02180-2]
The reaction of amines with an electrogenerated base. Improved synthesis of arylcarbamic esters
FEROCI, Marta;INESI, ACHILLE;
2000
Abstract
The electrogenerated base of 2-pyrrolidone reacts with amines and anilines yielding the corresponding alkyl and aryl carbamates, after addition of carbon dioxide and ethyl iodide. Arylcarbamic esters are obtained in very good yields under mild reaction conditions with respect to the methods so far reported. (C) 2000 Elsevier Science Ltd. All rights reserved.File allegati a questo prodotto
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