The deprotonation of the radical cation of p-cresol, a model of tyrosine residues, has been studied kinetically in the gas phase. The reaction has revealed the operation of competitive deprotonation sites depending on the strength of the base, as shown by an FT-ICR study using d-labelling.

Gas phase regioselectivity in the deprotonation of p-cresol radical cation / Chiavarino, Barbara; Crestoni, Maria Elisa; Fornarini, Simonetta. - In: CHEMICAL PHYSICS LETTERS. - ISSN 0009-2614. - STAMPA. - 372:1-2(2003), pp. 183-186. [10.1016/s0009-2614(03)00398-1]

Gas phase regioselectivity in the deprotonation of p-cresol radical cation

CHIAVARINO, Barbara;CRESTONI, Maria Elisa;FORNARINI, Simonetta
2003

Abstract

The deprotonation of the radical cation of p-cresol, a model of tyrosine residues, has been studied kinetically in the gas phase. The reaction has revealed the operation of competitive deprotonation sites depending on the strength of the base, as shown by an FT-ICR study using d-labelling.
ft-icr mass spectrometry; proton transfer reactions; reaction mechanism
01 Pubblicazione su rivista::01a Articolo in rivista
Gas phase regioselectivity in the deprotonation of p-cresol radical cation / Chiavarino, Barbara; Crestoni, Maria Elisa; Fornarini, Simonetta. - In: CHEMICAL PHYSICS LETTERS. - ISSN 0009-2614. - STAMPA. - 372:1-2(2003), pp. 183-186. [10.1016/s0009-2614(03)00398-1]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/249924
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