The gas-phase reaction of Me3Si+ ions with acetylene is remarkably sensitive to the environment, leading to substitution products in radiolytic systems at atmospheric pressure and to rearranged adduct ions in the FT-ICR cell at 10-8 Torr, while seeming unproductive in an intermediate pressure range.

The trimethylsilylation of acetylene / Chiavarino, Barbara; Crestoni, Maria Elisa; Fornarini, Simonetta. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - STAMPA. - 2002:13(2002), pp. 1418-1419. [10.1039/b203587c]

The trimethylsilylation of acetylene

CHIAVARINO, Barbara;CRESTONI, Maria Elisa;FORNARINI, Simonetta
2002

Abstract

The gas-phase reaction of Me3Si+ ions with acetylene is remarkably sensitive to the environment, leading to substitution products in radiolytic systems at atmospheric pressure and to rearranged adduct ions in the FT-ICR cell at 10-8 Torr, while seeming unproductive in an intermediate pressure range.
gas phase ion chemistry; gas phase radiolysis; pressure effects; silacations
01 Pubblicazione su rivista::01a Articolo in rivista
The trimethylsilylation of acetylene / Chiavarino, Barbara; Crestoni, Maria Elisa; Fornarini, Simonetta. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - STAMPA. - 2002:13(2002), pp. 1418-1419. [10.1039/b203587c]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/248712
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