An intracluster proton-promoted reaction leading to a ligand switching in mixed NOq2 complexes of nitric acid and its derivatives is described. The proton affinity and the NOq2 binding energy are demonstrated to be the factors affecting the process, the trend of which is shown to reflect the peculiar properties of nitric acid and its derivatives.
Protonation induced ligand switching within NO2+ bound clusters / DE PETRIS, Giulia; Pepi, Federico. - In: CHEMICAL PHYSICS LETTERS. - ISSN 0009-2614. - STAMPA. - 285:5-6(1998), pp. 366-372. [10.1016/S0009-2614(97)01338-9]
Protonation induced ligand switching within NO2+ bound clusters.
DE PETRIS, GIULIA;PEPI, Federico
1998
Abstract
An intracluster proton-promoted reaction leading to a ligand switching in mixed NOq2 complexes of nitric acid and its derivatives is described. The proton affinity and the NOq2 binding energy are demonstrated to be the factors affecting the process, the trend of which is shown to reflect the peculiar properties of nitric acid and its derivatives.File allegati a questo prodotto
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