Van der Waals potential energy calcns. for conformational anal. of butadiene-ethylene polymer (I) [25068-01-3] (contg. <5% butadiene) indicated the I chain was folded with the double bond lying in the fold; the double bond adapted itself inside a polymethylene chain without modifying appreciably the polyethylene lattice as well as the intramol. van der Waals energy. I tended to crystallize in the orthorhombic phase more stably than polyethylene as far as van der Waals forces are concerned.
Potential energy calculations of ethylene-butadiene copolymers / E., Cernia; G., Conte; D'Ilario, Lucio; Pavel, Nicolae Viorel; Giglio, Edoardo. - In: JOURNAL OF POLYMER SCIENCE. POLYMER CHEMISTRY EDITION. - ISSN 0360-6376. - STAMPA. - 13:(1975), pp. 125-131. [10.1002/pol.1975.170130113]
Potential energy calculations of ethylene-butadiene copolymers
D'ILARIO, LUCIO;PAVEL, Nicolae Viorel;GIGLIO, Edoardo
1975
Abstract
Van der Waals potential energy calcns. for conformational anal. of butadiene-ethylene polymer (I) [25068-01-3] (contg. <5% butadiene) indicated the I chain was folded with the double bond lying in the fold; the double bond adapted itself inside a polymethylene chain without modifying appreciably the polyethylene lattice as well as the intramol. van der Waals energy. I tended to crystallize in the orthorhombic phase more stably than polyethylene as far as van der Waals forces are concerned.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
