Azidoformates derived from chiral enol ethers, when irradiated, give 3,6-dioxazocan-2-one derivatives 7 by a highly diastereoselective intramolecular cycloaddition. The hydrolysis of 7 gives a single derivative of 2-aminocyclohexanone.
Optically pure 3,6-dioxazocan-2-one derivatives by intramolecular cycloaddition of azidoformates and their opening to substituted alpha-amino ketones / M., De Santis; Fioravanti, Stefania; Pellacani, Lucio; Tardella, Paolo Antonio. - In: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. - ISSN 1434-193X. - STAMPA. - -:(1999), pp. 2709-2711.
Optically pure 3,6-dioxazocan-2-one derivatives by intramolecular cycloaddition of azidoformates and their opening to substituted alpha-amino ketones
FIORAVANTI, Stefania;PELLACANI, Lucio;TARDELLA, Paolo Antonio
1999
Abstract
Azidoformates derived from chiral enol ethers, when irradiated, give 3,6-dioxazocan-2-one derivatives 7 by a highly diastereoselective intramolecular cycloaddition. The hydrolysis of 7 gives a single derivative of 2-aminocyclohexanone.File allegati a questo prodotto
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