family of totally synthetic, brush-type chiral stationary phases (CSPs) for HPLC applications are available through a simple and flexible methodol. based on the covalent attachment of chiral amines to oxirane-activated silica microparticles. Tailored CSPs for specific classes of compds. can be obtained by a proper choice of the optically active amine. Some typical features of the above phases are illustrated, with new results on the thermodn. of CSP-solute interactions and on the anal. of stereolabile compds.
Enantioselective chromatography on brush-type chiral stationary phases containing totally synthetic selectors: theoretical aspects and practical applications / Gasparrini, Francesco; Misiti, Domenico; Pierini, Marco; Villani, Claudio. - In: JOURNAL OF CHROMATOGRAPHY A. - ISSN 0021-9673. - STAMPA. - 724:(1996), pp. 79-90. [10.1016/0021-9673(95)01055-6]
Enantioselective chromatography on brush-type chiral stationary phases containing totally synthetic selectors: theoretical aspects and practical applications
GASPARRINI, Francesco;MISITI, Domenico;PIERINI, MARCO;VILLANI, Claudio
1996
Abstract
family of totally synthetic, brush-type chiral stationary phases (CSPs) for HPLC applications are available through a simple and flexible methodol. based on the covalent attachment of chiral amines to oxirane-activated silica microparticles. Tailored CSPs for specific classes of compds. can be obtained by a proper choice of the optically active amine. Some typical features of the above phases are illustrated, with new results on the thermodn. of CSP-solute interactions and on the anal. of stereolabile compds.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
