Substitution of a single H atom of an alkane by a diatomic [Cl−Cl]+chlorinium ion was demonstrated in the gas phase and by mass spectrometric and theoretical methods (see scheme). This is the first example of a new dihalogenation reaction. In addition to protonated dichloromethane a, the new isomer b was prepared and structurally characterized by MIKE, CAD, and FT-ICR mass spectrometry as well as calculations up to the CCSD(T) level of theory
Gaseous [CH3-Cl-Cl]+ ions from the reaction of methane with Cl3+, the first example of a new dihalogenation process. Formation and characterization of CH3Cl2+ isomers by experimental and theoretical methods / Cacace, Fulvio; DE PETRIS, Giulia; Pepi, Federico; M., Rosi; Troiani, Anna. - In: CHEMISTRY-A EUROPEAN JOURNAL. - ISSN 0947-6539. - STAMPA. - 5:9(1999), pp. 2750-2756. [10.1002/(SICI)1521-3765(19990903)5:9<2750::AID-CHEM2750>3.3.CO;2-K]
Gaseous [CH3-Cl-Cl]+ ions from the reaction of methane with Cl3+, the first example of a new dihalogenation process. Formation and characterization of CH3Cl2+ isomers by experimental and theoretical methods.
CACACE, Fulvio;DE PETRIS, GIULIA;PEPI, Federico;TROIANI, Anna
1999
Abstract
Substitution of a single H atom of an alkane by a diatomic [Cl−Cl]+chlorinium ion was demonstrated in the gas phase and by mass spectrometric and theoretical methods (see scheme). This is the first example of a new dihalogenation reaction. In addition to protonated dichloromethane a, the new isomer b was prepared and structurally characterized by MIKE, CAD, and FT-ICR mass spectrometry as well as calculations up to the CCSD(T) level of theoryI documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
