Electrochemical reduction of diselenides allows the formation of selenide anions which react with different chloroformates yielding the corresponding selenocarbonates in moderate to very high yields. The reaction is general and prevents the use of further reagents or drastic reaction conditions. Moreover the use of labile or air sensitive precursors such as selenides is avoided.
Electrochemical synthesis of selenocarbonates / A., LA GROIA; Feroci, Marta; Inesi, Achille; L., Rossi. - In: LETTERS IN ORGANIC CHEMISTRY. - ISSN 1570-1786. - STAMPA. - 3:(2006), pp. 854-856. [10.2174/157017806779117003]
Electrochemical synthesis of selenocarbonates
FEROCI, Marta;INESI, ACHILLE;
2006
Abstract
Electrochemical reduction of diselenides allows the formation of selenide anions which react with different chloroformates yielding the corresponding selenocarbonates in moderate to very high yields. The reaction is general and prevents the use of further reagents or drastic reaction conditions. Moreover the use of labile or air sensitive precursors such as selenides is avoided.File allegati a questo prodotto
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