The isolation of complexes 2 and 3, unambiguously characterized by single-crystal X-ray diffraction, demonstrates that nucleophilic additions to the aluminum-coordinated imino bond of salophen complex 1 can be achieved under very mild conditions.
Evidence of the facile hydride and enolate addition to the imine bond of an aluminum-salophen complex / M., Cametti; DALLA CORT, Antonella; M., Colapietro; Portalone, Gustavo; L., Russo; K., Rissanen. - In: INORGANIC CHEMISTRY. - ISSN 0020-1669. - STAMPA. - 46:(2007), pp. 9057-9059. [10.1021/ic701521s]
Evidence of the facile hydride and enolate addition to the imine bond of an aluminum-salophen complex
DALLA CORT, Antonella;PORTALONE, Gustavo;
2007
Abstract
The isolation of complexes 2 and 3, unambiguously characterized by single-crystal X-ray diffraction, demonstrates that nucleophilic additions to the aluminum-coordinated imino bond of salophen complex 1 can be achieved under very mild conditions.File allegati a questo prodotto
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