Suitable electrochemical methodologies for the generation of cyanomethyl anion and some electrochemically induced cyanomethylation reactions of electrophilic substrates are described and discussed. In addition, the electrochemical syntheses of carbamates and chiral oxazolidin-2-ones (under mild conditions and avoiding the use of hazardous chemicals), via a new carboxylating reagent (CH2CN–/CO2), are reported in this article.
The Electrogenerated Cyanomethyl Anion in Organic Synthesis / Rossi, L.; Feroci, Marta; Inesi, Achille. - In: MINI-REVIEWS IN ORGANIC CHEMISTRY. - ISSN 1570-193X. - STAMPA. - 2:(2005), pp. 343-357. [10.2174/1570193052774135]
The Electrogenerated Cyanomethyl Anion in Organic Synthesis
FEROCI, Marta;INESI, ACHILLE
2005
Abstract
Suitable electrochemical methodologies for the generation of cyanomethyl anion and some electrochemically induced cyanomethylation reactions of electrophilic substrates are described and discussed. In addition, the electrochemical syntheses of carbamates and chiral oxazolidin-2-ones (under mild conditions and avoiding the use of hazardous chemicals), via a new carboxylating reagent (CH2CN–/CO2), are reported in this article.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
